Product ID:CLEAN CROP CARBARYL 4 L INSECTICIDE
MSDS Date:03/02/1995
FSC:6840
NIIN:01-104-0887
MSDS Number: BWZMK

PLATTE CHEMICAL CO., UNITED AGRA PRODUCTS

150 S. MAIN ST.
FREMONT, NE 68025-5674
US

Emergency Phone: 303-356-4400

Info Phone: 303-356-4400

Cage: 65551

PLATTE CHEMICAL CO., UNITED AGRA PRODUCTS

FREMONT, NE 68025-5674 US

Telephone: 303-356-4400/INFO 402-727-8222

Cage: 65551

CARBARYL (SEVIN) (SARA 313) (CERCLA)

CAS: 63-25-2

RTECS: FC5950000

Fraction By Weight: 43.2%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3; 9495

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

INERT INGREDIENTS

Fraction By Weight: 56.8%

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 230 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- MAY BE FATAL IF SWALLOWED. HARMFUL
IF ABSORBED THROUGH SKIN OR INHALED. CAUSES EYE IRRITATION &
BLURRED VISION. CAUSES REVERSIBLE CHOLINE STERASE INHIBITION. IN
SEVERE POISONING, RESPIRATORY DEPRESSION & CONVULSIONS MAY OCCUR.
CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NAUSEA, VOMITING, ABDOMINAL PAIN, DIARRHEA,
PINPOINT PUPILS, BLURRED VISION, PROFUSE SWEATING, SALIVATION,
TREMOR, MUSCLE TWITCHING, TEMPORARY PARALYSIS, IRRITATION,
RESPIRATORY DEPRESSION, CONVULSION S, TEARING AND REDNESS
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING CHRONIC
CARDIOVASCULAR OR RESPIRATORY DISEASE, LEADING TO RESPIRATORY
DIFFICULTY, PULMONARY EDEMA AND CYANOSIS.

First Aid:GET MEDICAL HELP IMMEDIATELY IN ALL CASES OF POISONING.
EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN.
SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE
CPR/OXYGEN IF NEEDED. ORAL:IF CONSCIOUS, DRINK 1-2 GLASSES OF
WATER & INDUCE VOMITING. NEVER INDUCE VOMITING/GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN/POISON CONTROL
CENTER IMMEDIATELY.

Flash Point Method:COC
Flash Point:380F,193C
Lower Limits:0.02 OZ/CUFT
Extinguishing Media:CARBON DIXOIDE OR DRY CHEMICAL FOR SMALL FIRE;
WATER SPRAY OR FOAM FOR LARGE FIRES.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-
APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN THE POSITIVE PRESSURE MODE. STAY UPWIND.
Unusual Fire/Explosion Hazard:CONTAINER MAY BURST. IF WATER IS USED TO
FIGHT FIRE OR COOL CONTAINERS, CONTAIN RUN-OFF BY DIKING TO PREVENT
CONTAMINATION OF WATER SUPPLIES (MARINE POLLUTANT).

Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING AND
EQUIPMENT. ABSORB SPILLS WITH CLAY AND TRANSFER TO PROPER CONTAINER
FOR LATER DISPOSAL. MARINE POLLUTANT. DO NOT FLUSH TO SEWER. DO NOT
CONTAMINATE ENVIRONMENT . DECONTAMIANTE TOOLS AND EQUIPMENT.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE UNUSED PRODUCT IN ORIGINAL
CONTAINER ONLY, IN COOL, DRY AREA OUT OF REACH OF CHILDREN AND
ANIMALS. DO NOT STORE WHERE TEMPERATURES EXCEED 100F.
Other Precautions:THIS PRODUCT IS EXTREMELY TOXIC TO AQUATIC AND
ESTUARINE INVERTEBRATES. DO NOT CONTAMINATE WATER, FOOD OR FEED BY
STORAGE OR DISPOSAL. AVOID CONTAMINATING WATER BY CLEANING OF
EQUIPMENT OR DISPOSAL OF WASTE. DO NOT INGEST. AVOID ANY CONTACT

Respiratory Protection:WEAR A NIOSH-APPROVED RESPIRATOR FOR CARBAMATE
PESTICIDES DUST OR MIST WHEN HANDLING SPILLS OR LEAKS, OR WHEN
AIRBORNE CONCENTRATIONS EXCEED ALLOWABLE EXPOSURE LIMITS.
Ventilation:MECHANICAL (GENERAL) VENTILATION. USE LOCAL EXHAUST FOR
CONFINED WORK AREAS.
Protective Gloves:RUBBER OR LATEX
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, LONG PANTS,
LONG-SLEEVED SHIRT, HAT, RUBBER BOOTS
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
NOTE TO PHYSICIAN: CARBARYL IS A CHOLINESTERASE INHIBITOR. IF
SWALLOWED, GASTRIC LAVAGE MAY BE PERFORMED. IN MILD CASES OF
POISONING, 1-2 MG OF ATROPINE SULFATE MAY BE INJECTED
INTRAMUSCULARLY EVERY 1 0 MINUTES UNTIL FULLY ATROPINIZED. IN
SEVERE CASES, USE 2-4 MG EVERY 10 MINUTES. AVOID NARCOTICS, OTHER
SEDATIVE, 2-PAM.

HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:212F,100C
Decomp Temp:Decomp Text:>100F,>38C
Vapor Pres:17.8 @ 68F
Vapor Density:APPROX 0.6
Spec Gravity:1.11
pH:4.2
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:DISPERSIBLE
Appearance and Odor:OFF-WHITE TO CREAM COLORED AQUEOUS SUSPENSION, MILD
ODOR
Percent Volatiles by Volume:57

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXTENDED STORAGE AT TEMPERATURES IN EXCESS
OF 100 DEGREES F.
Hazardous Decomposition Products:OXIDES OF NITROGEN, CARBON AND SULFUR,
AND METHYL ISOCYANATE MAY BE PRODUCED UPON THERMAL DECOMPOSITION.

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS. REPORTABLE QUANTITY FOR
CARBARYL IS 100 LBS. EMPTY CONTAINERS MAY BE DISPOSED IN A SANITARY
LANDFILL OR BURNED IF ALLOW ED. IF BURNED, STAY OUT OF SMOKE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.